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dc.contributor.authorGámez-Valenzuela, Sergio
dc.contributor.authorPonce-Ortiz, Rocío 
dc.contributor.authorGómez-Lor, Berta
dc.contributor.authorRuiz-Delgado, María del Carmen 
dc.date.accessioned2022-07-07T08:27:15Z
dc.date.available2022-07-07T08:27:15Z
dc.date.created2022
dc.date.issued2022-06-30
dc.identifier.urihttps://hdl.handle.net/10630/24576
dc.description.abstractOrganic semiconductors have emerged as an important class of materials that offer interesting prospects for high throughput, low-cost and flexible electronic circuits. In this sense, triindole-based systems have demonstrated great potential as p-type semiconductors in organic field-effect transistors (OFETs).[1] Recently, we have performed a combined experimental and theoretical study of three new crystalline N-trimethyltriindoles endowed with different functionalities at 3, 8 and 13 positions, either unsubstituted or with three methoxy or acetyl groups (Figure 1a), with the main goal of exploring the correlation between the electronic nature of the substituents and their solid-state organization, electronic properties and semiconductor behavior.[2] On the other hand, the design and synthesis of covalent organic framework materials (constructed from the union of different covalently linked conjugated platforms) are being deeply investigated in organic electronics.[3] In line with this , we have also investigated how the structural and the electronic properties of 2D triindole-based polymers (Figure 1b) can be modulated by the (i) modification of the linkage position from para (T2) to meta (T3), (ii) by the insertion of different π-bridges between the cores and (iii) by the increment of the number of π-bridges from 3 to 6 units (T2,3).[4] Overall, the results of this work open the door to the control of the degree of the π-conjugation for their subsequent synthesis and real application in organic electronic devices.es_ES
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.es_ES
dc.language.isoenges_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectSemiconductores orgánicoses_ES
dc.subject.otherTriindolees_ES
dc.subject.otherorganic semiconductorses_ES
dc.subject.otherDFT-calculationses_ES
dc.subject.otherOFETses_ES
dc.subject.otherPorous polymerses_ES
dc.titleUntangling the eclectronic propierties of triindole-based semiconductorses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.centroFacultad de Cienciases_ES
dc.relation.eventtitleXXXVIII Reunión Bienal de la Real Sociedad Española de Químicaes_ES
dc.relation.eventplaceGranadaes_ES
dc.relation.eventdate30/06/2022es_ES
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*


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