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- Química Inorgánica, Cristalografía y Mineralografía - (QICM)
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Listar QICM - Artículos por autor "Infantes-Molina, Antonia"
Mostrando ítems 1-12 de 12
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2D Corrugated Magnesium Carboxyphosphonate Materials: Topotactic Transformations and Interlayer “Decoration” with Ammonia
Demadis, Konstantinos D.; Famelis, Nikos; Cabeza-Díaz, Aurelio; García-Aranda, Miguel Ángel; Pérez-Colodrero, Rosario Mercedes; Infantes-Molina, Antonia[et al.] (American Chemical Society, 2012-06-29)In this paper we report the synthesis and structural characterization of the 2D layered coordination polymer Mg(BPMGLY)(H2O)2 (BPMGLY = bis-phosphonomethylglycine, (HO3PCH2)2N(H)COO2−). The Mg ion is found in a slightly ... -
Bimetallic Niobium-Based Catalysts Supported on SBA-15 for Hydrodeoxygenation of Anisole
Ballesteros-Plata, Daniel; Barroso-Martín, Isabel; Medina Cervantes, Juan Andrés; Maciel, Carmen; Huirache-Acuña, Rafael; Rodríguez-Castellón, Enrique; Infantes-Molina, Antonia[et al.] (ACS, 2021-12-17)The effect of adding iron, cobalt or nickel to a prepared niobium-supported catalyst using mesoporous silica SBA-15 as a support was evaluated in the hydrodeoxygenation (HDO) reaction of anisole, chosen as a model compound ... -
“Breathing” in Adsorbate-Responsive Metal Tetraphosphonate Hybrid Materials
Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio; Olivera-Pastor, Pascual; Infantes-Molina, Antonia; Barouda, Eleni; Demadis, Konstantinos D.; García-Aranda, Miguel Ángel[et al.] (Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim, 2009-05-28)The structures of various layered calcium tetraphosphonates (CaH6DTMP; H8DTMP=hexamethyl- tetrakis(methylenephosphonic acid)), have been determined. Starting from CaH6DTMP·2H2O, thermal treatment and subsequent exposure ... -
Effect of the treatment with H3PO4 on the catalytic activity of Nb2O5 supported on Zr-doped mesoporous silica catalyst. Case study: glycerol dehydration.
García-Sancho, Cristina; Cecilia-Buenestado, Juan Antonio; Mérida-Robles, Josefa María; Santamaría-González, José; Moreno-Tost, Ramón; Infantes-Molina, Antonia; Maireles-Torres, Pedro Jesús[et al.] (Elsevier B.V., 2017-09-06)We have previously demonstrated the influence of the niobium species over the glycerol dehydration reaction and how the catalyst regeneration by thermal treatment modified the catalytic performance due to the transformation ... -
From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and waterfacilitated proton conductivity
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Vasileiou, Antonia; Papadaki, Maria; Olivera-Pastor, Pascual; Infantes-Molina, Antonia; Ramírez-Losilla, Enrique; Mezei, Gellert; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (The Royal Society of Chemistry, 2018-09)A family of alkali metal-based frameworks containing the tetraphosphonate ligand hexamethylenediamine- N,N,N′,N′-tetrakisIJmethylenephosphonic acid), HDTMP, is reported. A cation size-induced structural diversity, from ... -
Impact of the lanthanide size on the polymorphism and electrical properties of Ln5.4MoO11.1 (Ln = Nd, Sm and Gd)
Rubio-Vives, Rafael; Porras-Vázquez, José Manuel; Dos-Santos-Gómez, Lucía; Zamudio-García, Javier; Infantes-Molina, Antonia; Canales-Vázquez, J.; Marrero-López, David; Ramírez-Losilla, Enrique[et al.] (Elsevier, 2023)Mixed proton-electronic conductors are of great interest for high temperature electrochemical devices, such as hydrogen separation membranes. In this contribution, ceramics with composition Ln5.4MoO11.1 (Ln = Nd, Sm and ... -
Materials Design for N2O Capture: Separation in Gas Mixtures
Ballesteros-Plata, Daniel; Cecilia-Buenestado, Juan Antonio; Barroso-Martín, Isabel; Jiménez-Jiménez, José; Infantes-Molina, Antonia; Rodríguez-Castellón, Enrique[et al.] (IOAP-MDPI, 2022-11-29)The adsorption of greenhouse gases (GHG) as a method to reduce their emissions into the atmosphere is an alternative that is easier to implement industrially and cheaper than other existing technologies, such as chemical ... -
Modification of the Textural Properties of Chitosan to Obtain Biochars for CO2-Capture Processes
Barroso-Martín, Isabel; Cecilia-Buenestado, Juan Antonio; Vilarrasa García, Enrique; Ballesteros-Plata, Daniel; Jiménez Gómez, Carmen Pilar; Vílchez-Cózar, Álvaro; Infantes-Molina, Antonia; Rodríguez-Castellón, Enrique[et al.] (IOAP-MDPI, 2022-12-01)Three chitosans with different morphologies have been used (commercial chitosan powder, chitosan in film form and chitosan in globular form synthesized by the freeze-dried method) for the synthesis of biochars. The pyrolytic ... -
N2O Assisted Ethane Transformation into Ethylene Using NiO--CeO2--ZrO2 Catalysts
Sánchez, Ginebra; Dejoz, Ana M.; Fernández-Domene, Ramón; Barroso-Martín, Isabel; Ballesteros-Plata, Daniel; Infantes-Molina, Antonia; Cecilia-Buenestado, Juan Antonio; Rodríguez-Castellón, Enrique; López Nieto, José Manuel; Sánchez-Tovar, Rita; Solsona, Benjamín[et al.] (Wiley, 2024-11)NiO--CeO2 and NiO--CeO2--ZrO2 catalysts have been synthesized, electrochemically characterized (Mott-Schottky (MS) measurements and Electrochemical Impedance Spectroscopy), physicochemically characterized (by N2 adsorption, ... -
Ruthenium incorporation into hydrotalcites-derived mixed oxides for phenol hydrogenation: Role of Mg/Al molar ratio
Barroso-Martín, Isabel; Benmebirouk-Pareja, Nadia; Montaña, Maia; Cecilia-Buenestado, Juan Antonio; Infantes-Molina, Antonia; Rodríguez-Castellón, Enrique[et al.] (Elsevier, 2023-06)In this work the catalytic behaviour of Ru supported on mixed oxides derived from non-commercial hydrotalcites in phenol hydrogenation was studied in a batch reactor working at 30 bar and 200 °C. To this end, a set of ... -
Tailoring basic and acidic properties of MgAl hydrotalcite by fluoride anions: Effect on glycerol oligomerisation
Maderuelo-Solera, Rocío; Ledesma-Muñoz, A.L.; García-Sancho, Cristina; Cecilia-Buenestado, Juan Antonio; Infantes-Molina, Antonia; Mérida-Robles, Josefa María; Maireles-Torres, Pedro Jesús; Moreno-Tost, Ramón[et al.] (Elsevier, 2023)In this work, two families of catalysts based on mixed metal oxides derived from MgAl hydrotalcites were synthesized with a Mg/Al molar ratio of 3. On the one hand, in the first family, the fluoride anion was incorporated ... -
Zeolites synthesis from phyllosilicates and their performance for CO2 adsorption
Es Sih, Salima; Vilarrasa García, Enrique; De Azevedo, Diana Cristina Silva; Ballesteros-Plata, Daniel; Barroso-Martín, Isabel; Infantes-Molina, Antonia; Rodríguez-Castellón, Enrique; Franco-Duro, Francisco Ignacio; Cecilia-Buenestado, Juan Antonio[et al.] (Springer, 2024)Five phyllosilicates (kaolinite, montmorillonite, saponite, sepiolite and palygorskite) have been selected as starting materi- als for the synthesis of zeolites. Among them, kaolinite and montmorillonite display the lowest ...