Listar QICM - Artículos por título
Mostrando ítems 13-32 de 89
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Calcium aluminate cement conversion analysed by ptychographic nanotomography
(Elsevier, 2020-08-17)Calcium aluminate cements are used for special applications but are nowadays banned for general structural purposes due to the calcium aluminate hydrate conversion, that has led, for concretes fabricated with high water ... -
Chemistry and Mass Density of Aluminum Hydroxide Gel in Eco-Cements by Ptychographic X-ray Computed Tomography
(ACS, 2017)Eco-cements are a desirable alternative to ordinary Portland cements because of their lower CO2 footprints. Some ye’elimite-based ecocements are attracting a lot of interest. Understanding the reasons for the mechanical ... -
Clinkering and hydration of belite-ye'elimite-alite cement
(Elsevier, 2017)Some belite-ye´elimite-ferrite (BYF) cements present low mechanical strengths mainly due to the slow reactivity of belite. A solution to this problem may be the activation of BYF clinkers by preparing them with a coexistence ... -
Common Structural Features in Calcium Hydroxyphosphonoacetates. A High-Throughput Screening
(2011-03-11)R,S-Hydroxyphosphonoacetic acid (H3HPA) is an inexpensive multidentate organic ligand widely used for the preparation of organo-inorganic hybrid materials. There are reports of several crystal structures and the variability ... -
A comparative study of experimental configurations in synchrotron pair distribution function
(MDPI - Publisher of Open Access Journals, 2019-04-25)The identification and quantification of amorphous components and nanocrystalline phases with very small crystal sizes, smaller than ~3 nm, within samples containing crystalline phases is very challenging. However, this ... -
Crystal engineering in confined spaces. A novel method to grow crystalline metal phosphonates in alginate gel systems
(The Royal Society of Chemistry, 2012)In this paper we report a crystal growth method for metal phosphonate frameworks in alginate gels. It consists of a metalcontaining alginate gel, in which a solution of phosphonate ligand is slowly diffused. Crystals of ... -
Difracción de rayos-x (DRX) y cementos: desde la investigación hasta el control de calidad
(2019-06-20)Los materiales de construcción son componentes complejos de gran interés comercial. Por ello, el conocimiento cuantitativo de su mineralogía a través de la difracción de rayos X (DRX) es de crucial importancia para optimizar ... -
Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties
(American Chemical Society, 2011-09-27)A family of M-VP (M = Ni, Co, Cd, Mn, Zn, Fe, Cu, Pb; VP = vinylphosphonate) and M-PVP (M = Co, Cd; PVP = phenylvinylphosphonate) materials have been synthesized by hydrothermal methods and characterized by FTIR, elemental ... -
Durability and performance of CGO barriers and LSCF cathode deposited by spray-pyrolysis
(Elsevier, 2018-03-19)Ce0.9Gd0.1O1.95 (CGO) protective layers are prepared by two different methods to prevent the reaction between the Zr0.84Y0.16O1.92 (YSZ) electrolyte and the La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) cathode. In the first method, ... -
Effect of boron and water-to-cement ratio on the performances of laboratory prepared Belite-Ye'elimite-Ferrite (BYF) cements
(2021)The effect of superplasticiser, borax and the water-to-cement ratio on BYF hydration and mechanical strengths has been studied. Two laboratory-scale BYF cements—st-BYF (with -C2S and orthorhombic C4A3 S) and borax-activated ... -
Effect of calcium sulfate source on the hydration of calcium sulfoaluminate eco-cement
(2014)The availability of cements, including eco-cements, with tailored mechanical properties is very important for special applications in the building industry. Here we report a full study of the hydration of calcium sulfoaluminate ... -
Effect of Zn addition on the structure and electrochemical properties of codoped BaCe0.6Zr0.2Ln0.2O3-δ (Ln=Y, Gd, Yb) proton conductors
(Elsevier, 2018-05-02)In this work, BaCe0.6Zr0.2Y0.2-xYbxO3-δ and BaCe0.6Zr0.2Gd0.2-xYbxO3-δ (x=0–0.20), proton conducting materials are prepared by the freeze-drying precursor method. The sintering conditions were optimized by adding ... -
The effects of MgO, Na2O and SO3 on industrial clinkering process: phase composition, polymorphism, microstructure and hydration, using a multidisciplinary approach
(2019-07-02)The present investigation deals with how minor elements (their oxides: MgO, Na2O and SO3) in industrial kiln feeds affect (i) chemical reactions upon clinkering, (ii) resulting phase composition and microstructure ... -
Effects of sulfates on the hydration of Portland cement – A review
(2021)Presented within is a critical overview of the effect of sulfates on cement hydration, properties, and optimum sulfate content in Portland cement. Calcium sulfate is used in Portland cement to control the C3A reaction ... -
Experimental and theoretical high pressure study of calcium hydroxyaluminate phases
(Elsevier, 2017)Five calcium hydroxyaluminate phases have been investigated by synchrotron powder diffraction at high-pressure: two hydrogarnets, kuzelite, stratlingite and ettringite. The obtained bulk modulus, K0, for kuzelite, stratlingite ... -
From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and waterfacilitated proton conductivity
(The Royal Society of Chemistry, 2018-09)A family of alkali metal-based frameworks containing the tetraphosphonate ligand hexamethylenediamine- N,N,N′,N′-tetrakisIJmethylenephosphonic acid), HDTMP, is reported. A cation size-induced structural diversity, from ... -
Guest Molecule-Responsive Functional Calcium Phosphonate Frameworks for Tuned Proton Conductivity
(American Chemical Society, 2014-03-18)We report the synthesis, structural characterization, and functionality of an open-framework hybrid that combines Ca2+ ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl) isophthalic acid (PiPhtA). Ca-PiPhtA-I ... -
High pressure and temperature spinning capillary cell for in-situ synchrotron X-ray powder diffraction
(2019)In situ research of materials under moderate pressures (hundreds of bar) is essential in many scientific fields. These range from gas sorption to chemical and biological processes. One industrially important discipline is ... -
High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework
(American Chemical Society, 2012-07-03)Multifunctional materials, especially those combining two or more properties of interest, are attracting immense attention due to their potential applications. MOFs, metal organic frameworks, can be regarded as multifunctional ... -
High-Throughput Synthesis of Pillared-Layered Magnesium Tetraphosphonate Coordination Polymers: Framework Interconversions and Proton Conductivity Studies
(MDPI, www.mdpi.com/journal/inorganics, 2018-09-11)Novel pillared-layered framework materials were synthesized by high-throughput or microwave-assisted methodology that contain Mg2+ and the zwitterionic linker HDTMP (hexamethylenediamine-N,N,N0,N0-tetrakis(methylenephosphonic ...