Listar QICM - Artículos por título
Mostrando ítems 46-65 de 146
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High pressure and temperature spinning capillary cell for in-situ synchrotron X-ray powder diffraction
Fraga, Edmundo; Yáñez, Armando; Zea-Garcia, Jesus D.; Gomez-de-la-Torre, Maria de los Angeles
; Cuesta-Garcia, Ana Maria; Valcárcel-Fernández, Ricardo; Farré-París, Francesc; Malfois, Marc; Aranda, M.A.G.[et al.] (2019)
In situ research of materials under moderate pressures (hundreds of bar) is essential in many scientific fields. These range from gas sorption to chemical and biological processes. One industrially important discipline is ... -
High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework
Perez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Losilla, Enrique R.; Hernández Alonso, Daniel; G. Aranda, Miguel Ángel; León-Reina, Laura; Rius, Jordi; Demadis, Konstantinos D.; Moreau, Bernard; Villemin, Didier; Palomino, Miguel; Rey, Fernando; Cabeza-Diaz, Aurelio[et al.] (American Chemical Society, 2012-07-03)
Multifunctional materials, especially those combining two or more properties of interest, are attracting immense attention due to their potential applications. MOFs, metal organic frameworks, can be regarded as multifunctional ... -
High-Throughput Synthesis of Pillared-Layered Magnesium Tetraphosphonate Coordination Polymers: Framework Interconversions and Proton Conductivity Studies
Perez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Barouda, Eleni; Papadaki, Maria; Papathanasiou, Konstantinos E.; Hernández Alonso, Daniel; Rius, Jordi; García-Aranda, Miguel Ángel; Ramirez-Losilla, Enrique; Olivera-Pastor, Pascual; Demadis, Konstantinos D.; Cabeza-Diaz, Aurelio[et al.] (MDPI, www.mdpi.com/journal/inorganics, 2018-09-11)
Novel pillared-layered framework materials were synthesized by high-throughput or microwave-assisted methodology that contain Mg2+ and the zwitterionic linker HDTMP (hexamethylenediamine-N,N,N0,N0-tetrakis(methylenephosphonic ... -
Highly efficient La0.8Sr0.2MnO3-δ - Ce0.9Gd0.1O1.95 nanocomposite cathodes for solid oxide fuel cells
Dos Santos-Gómez, Lucía; Zamudio-García, Javier; Porras-Vázquez, José Manuel; Losilla, Enrique R.; Marrero-López, David (Elsevier, 2017-12-15)
La0.8Sr0.2MnO3-δ-Ce0.9Gd0.1O1.95 (LSM-CGO) nanostructured cathodes are successfully prepared in a single process by a chemical spray-pyrolysis deposition method. The cathode is composed of nanometric particles of approximately ... -
Hydration and interactions between pure and doped C3S and C3A in the presence of different calcium sulfates
Andrade Neto, José da Silva; de Matos, Paulo R.; Gomez-de-la-Torre, Maria de los Angeles; Campos, Carlos E. M.; Torres, Sandro M.; Monteiro, Paulo J. M.; Kirchheim, Ana Paula[et al.] (2022)
This research studied the hydration of C3S-C3A-calcium sulfate systems made of combinations of two C3S (pure triclinic and Al-doped monoclinic), two C3A (pure cubic C3A and Na-doped orthorhombic), and two calcium sulfates ... -
Hydration development and thermal performance of calcium sulphoaluminate cements containing microencapsulated phase change materials
Sanfelix, Susana G.; Zea-Garcia, Jesus D.; Londono-Zuluaga, Diana; Santacruz-Cruz, Maria Isabel; Gomez-de-la-Torre, Maria de los Angeles; Kjøniksen, Anna-Lena[et al.] (2020-03-24)
Microencapsulated phase change materials (MPCM) incorporated in buildings walls can reduce indoor temperature fluctuations, conserving energy and enhancing thermal comfort. MPCM were incorporated in calcium sulphoaluminate ... -
Hydration mechanisms of Ba-doped ye’elimite: effect of Ba/Ca ratio on hydration behavior
Zhao, Piqi; Bao, Xingyuan; Chen, Heng; Wang, Shoude; Lu, Lingchao; Gomez-de-la-Torre, Maria de los Angeles; Cheng, Xin[et al.] (2020-09-28)
Than stoichiometric one. However, the hydration mechanism is not well understood, in particular for the effect of Ba/Ca ratio on hydration behavior. To shed light on this issue, high purity C4-xBxA3$ samples with designed ... -
Hydration mechanisms of two polymorphs of synthetic ye'elimite
Cuesta-Garcia, Ana Maria; Álvarez-Pinazo, Gema; Sanfeliz-Garcia, Susana; Peral, Inma; García-Aranda, Miguel Ángel; Gomez-de-la-Torre, Maria de los Angeles[et al.] (Elsevier, 2014-05-26)
Ye'elimite is the main phase in calcium sulfoaluminate cements and also a key phase in sulfobelite cements. However, its hydrationmechanismis not well understood. Here we reported newdata on the hydration behavior of ... -
Hydration of Belite-Ye’elimite-Ferrite(BYF) cements with different calcium sulfate sources
Álvarez-Pinazo, Gema; Santacruz-Cruz, Maria Isabel; García-Aranda, Miguel Ángel; Gomez-de-la-Torre, Maria de los Angeles (ICE publishing, 2016-07)
Belite-Ye’elimite-Ferrite cements, BYF, are a sustainable alternative to OPC to reduce CO2 emissions. The aim of this research is to understand the influence of the sulfate source on the hydration of two laboratory-prepared ... -
Hydration of C3S and Al-doped C3S in the presence of gypsum
Andrade Neto, José da Silva; Rodríguez, Erick D.; Monteiro, Paulo J. M.; Gomez-de-la-Torre, Maria de los Angeles; Kirchheim, Ana Paula (sciencedirect, 2022)
A complete understanding of the effect of gypsum on the C3S hydration and the role of aluminum has not been achieved. The effects of gypsum (at 2.5 wt% and 5.0 wt%) on the hydration of tricalcium silicate (C3S) and aluminum-doped ... -
Hydration of C4AF in the presence of other phases: A synchrotron X-ray powder diffraction study
Cuesta-Garcia, Ana Maria; Santacruz-Cruz, Maria Isabel; Sanfeliz-Garcia, Susana; Fauth, François; García-Aranda, Miguel Ángel; Gomez-de-la-Torre, Maria de los Angeles[et al.] (Elsevier, 2015)
Hydration behaviour of C4AF in selected experimental conditions has been determined. C4AF has been hydrated in the absence and presence of gypsum, two polymorphs of ye’elimite and different water/solid ratios. C4AF in ... -
Hydration Reactions and Mechanical Strength Developments of Iron- Rich Sulfobelite Eco-cements
Álvarez-Pinazo, Gema; Santacruz-Cruz, Maria Isabel; León-Reina, Laura; García-Aranda, Miguel Ángel; Gomez-de-la-Torre, Maria de los Angeles (2013)
Belite calcium sulfoaluminate (BCSA) cements are low-CO2 building materials. However, their hydration behavior and its effect on mechanical properties have still to be clarified. Here, we report a full multitechnique study ... -
Hydration studies of calcium sulfoaluminate cements blended with fly ash
García-Maté, Marta; Gomez-de-la-Torre, Maria de los Angeles; León-Reina, Laura; García-Aranda, Miguel Ángel; Santacruz-Cruz, Maria Isabel (Elsevier, 2013)
The main objective of this work is to study the hydration and properties of calciumsulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray ... -
In situ hydration imaging study of a ye'elimite paste by ptychographic x-ray computed tomography
Cuesta-Garcia, Ana Maria; Gomez-de-la-Torre, Maria de los Angeles; Santacruz-Cruz, Maria Isabel; Trtik, Pavel; Da Silva, Julio C.; Cuesta-Garcia, Ana Maria; Holler, Mirko; García-Aranda, Miguel Ángel[et al.] (2017)
Eco-cements are a desirable alternative to ordinary Portland cements because of their lower CO2 footprints. For instance, the manufacture of Calcium SulfoAluminate (CSA) cements is more environmentally friendly than that ... -
In-situ early-age hydration study of sulfobelite cements by synchrotron powder diffraction
Álvarez-Pinazo, Gema; Cuesta-Garcia, Ana Maria; García-Maté, Marta; Santacruz-Cruz, Maria Isabel; Ramirez-Losilla, Enrique; Sanfélix, Susana G; Fauth, François[et al.] (Karen Scrivener, 2014)
Eco-friendly belite calcium sulfoaluminate (BCSA) cement hydration behavior is not yet well understood. Here,we report an in-situ synchrotron X-ray powder diffraction study for the first hours of hydration of BCSA ... -
In-situ laboratory X-ray diffraction applied to assess cement hydration
de Matos, Paulo R.; Andrade Neto, José da Silva; Jansen, Daniel; Gomez-de-la-Torre, Maria de los Angeles; Kirchheim, Ana Paula; Campos, Carlos E. M.[et al.] (sciencedirect, 2022)
In-situ X-ray diffraction (XRD) is a powerful tool to assess the hydration of cementitious materials, providing time-resolved quantitative analysis with reasonable accuracy without disturbing sample. However, the lack ... -
Influence of curing temperature on belite cement hydration: a comparative study with Portland cement
Shirani, Shiva; Cuesta-García, Ana María; Morales-Cantero, Alejandro; Gomez-de-la-Torre, Maria de los Angeles; P. Olbinado, Margie; García-Aranda, Miguel Ángel[et al.] (Elsevier, 2021-05-24)
Belite cements (BCs) could be a more sustainable binder than Portland cements (PCs) but adequate knowledge of the hydration features has still to be built. In particular, the mild curing hydration temperature effects have ... -
Influence of fly ash blending on hydration and physical behavior of Belite-Alite-Ye'elimite cements
Londono-Zuluaga, Diana; Tobón, Jorge Iván; García-Aranda, Miguel Ángel; Santacruz-Cruz, Maria Isabel; Gomez-de-la-Torre, Maria de los Angeles (2018-10-19)
A cement powder, composed of belite, alite and ye’elimite, was blended with 0, 15 and 30 wt% of fly ash and the resulting lended cements were further characterized. During hydration, the presence of fly ash caused the ... -
Influence of morphology of zirconium-doped mesoporous silicas on 5-hydroxymethylfurfural production from mono-, di- and polysaccharides
Mérida Morales, Sandra; Garcia-Sancho, Cristina; Oregui-Bengoechea, Mikel; Ginés-Molina, María José; Cecilia-Buenestado, Juan Antonio; Arias, Pedro Luis; Moreno-Tost, Ramon; Maireles-Torres, Pedro Jesús[et al.] (Elsevier B.V., 2020-02-21)
Different zirconium-doped mesoporous silicas (Zr-KIT-6, Zr-SBA-15, Zr-MCM-41 and Zr-HMS) were synthesized and evaluated in the glucose dehydration to 5-hydroxymethylfurfural (HMF). A Si/Zr molar ratio of 5 was chosen for ... -
Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets
Palacios Corella, Mario; Fernández Espejo, Alejandro; Bazaga-García, Montse; Ramirez-Losilla, Enrique; Cabeza-Diaz, Aurelio; Clemente-León, Miguel; Coronado, Eugenio[et al.] (ACS publications, 2017-11-01)
The syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O ...