Portland-based Limestone Calcined Clay Cements (LC3) are attracting a lot of the attention from scholars
and field applications due to the reduction in CO2 emissions. However, their low mechanical strengths at
early ages are a key bottleneck for their widespread use. Calcined clays can also lead to a strong reduction
of the fluidity in the first hours after mixing, which is an important second drawback. Here, these two issues
have been addressed. Three LC3 binders were prepared based on a PC-52.5R cement and three calcined
clays, with variable amounts of kaolinite in the raw materials ranging 29-74 wt%. The particle sizes of the
calcined clays were adjusted by milling to Dv,50=13±2 μm. The results show that the loss of fluidity of LC3
mortars during the first hours can be solved by a recently developed PCE-based superplasticizer,
specifically tailored for this application. Moreover, the compressive strengths at 1 day for LC3 mortars have
been boosted by a C-S-H nucleation seeding admixture and the gains are maintained at 28 days. It is noted
that the compressive strengths at 1 day and room temperature were increased by 45-100 %, when compared
to the corresponding unseeded mortars.
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