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Cation template assisted oligoethylene glycol desymmetrization by intramolecular Cannizzaro reaction of topologically remote aldehydes.
| dc.contributor.author | Ruiz-Sanchez, Antonio Jesus | |
| dc.contributor.author | Vida-Pol, Yolanda | |
| dc.contributor.author | Suau Suárez, Rafael | |
| dc.contributor.author | Pérez-de-Inestrosa-Villatoro, Ezequiel | |
| dc.date.accessioned | 2024-09-25T06:41:43Z | |
| dc.date.available | 2024-09-25T06:41:43Z | |
| dc.date.issued | 2008 | |
| dc.identifier.uri | https://hdl.handle.net/10630/33122 | |
| dc.description | Política de acceso abierto tomada de: https://v2.sherpa.ac.uk/id/publication/15869 | es_ES |
| dc.description.abstract | Oligoethylene glycol chains containing 2–5 ethylene glycol units, and possessing a benzyl alcohol and a benzoic acid end groups, can be quantitatively obtained by intramolecular Cannizzaro reaction of the corresponding remote benzaldehyde end groups. The process is quite effective if a complex with an appropriate cation is formed to allow the two aldehyde groups to be spatially confined near enough each other for the intramolecular redox process. | es_ES |
| dc.language.iso | eng | es_ES |
| dc.publisher | Elsevier | es_ES |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.subject | Aldehídos | es_ES |
| dc.subject.other | Oligoethylene glycol desymmetrization | es_ES |
| dc.subject.other | Cannizzaro reaction | es_ES |
| dc.subject.other | Cation template | es_ES |
| dc.title | Cation template assisted oligoethylene glycol desymmetrization by intramolecular Cannizzaro reaction of topologically remote aldehydes. | es_ES |
| dc.type | journal article | es_ES |
| dc.centro | Facultad de Ciencias | es_ES |
| dc.identifier.doi | 10.1016/j.tet.2008.10.015 | |
| dc.type.hasVersion | AM | es_ES |
| dc.departamento | Química Analítica | |
| dc.rights.accessRights | open access | es_ES |