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dc.contributor.authorBerenguer-Betrian, Raul 
dc.contributor.authorGarcía-Mateos, Francisco
dc.contributor.authorRodriguez-Mirasol, Jose 
dc.contributor.authorCordero, Tomás 
dc.date.accessioned2014-07-28T09:06:41Z
dc.date.available2014-07-28T09:06:41Z
dc.date.created2014-07
dc.date.issued2014-07-28
dc.identifier.urihttp://hdl.handle.net/10630/7941
dc.description.abstractLignin is (and will be) an important co-product in many lignocellulosic biomass-derived industries, such as pulp and paper mills (and the future biorefineries, when the concept of bio-economy be developed). The development of high-value products from lignin could mean a significant opportunity to reduce the associated costs and the environmental impacts of these industries [1]. In this sense, a new method to produce novel sub-micrometer carbon fibers and interconnected fibrous carbon webs materials (FCMs), showing unique advanced properties for different applications, by electrospinning [2] of phosphorous-containing lignin solutions is studied in this work. The different FCMs were prepared by electrospinning of Alcell lignin solutions with and without P–containing compounds, followed by stabilization and carbonization at different temperatures. For comparison purposes, equivalent lignin-based powdery carbon materials (PCMs) were also prepared from lignin powder without the electrospinning step. The different samples were characterized by N2 and CO2 adsorption, SEM, TEM, XRD, Raman, XPS, TPD and TG analysis. In the absence of P-containing groups, electrospun carbon fibers are continuous and linear (Fig 1.a), and show a specific surface area of 700 m2/g, much higher than that of carbon prepared in powdery shape (70 m2/g). The presence of P precursors in the lignin solution re-markably affects the electrospinning, sta-bilization and carbo-nization processes. By a suitable control of the stabilization heating rate, continuous and curly carbon fibers (Fig 1.b) or interconnected carbon fibrous webs (Fig 1.c) can be produced. In addition, the presence of 30wt% of P-containing compound in the lignin solution increases the specific surface area up to 1500 m2/g and enhances the oxidation resistance of the FCMs at high temperatures, what have been found very interesting for different applications, such as catalysis, adsorption and energy storage and conversion. These properties cannot be obtained in lignin-based carbon powders, even by using an 80wt% of P-containing compound for their chemical activation (1100 m2/g).es_ES
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Andalucía Tech.es_ES
dc.language.isoenges_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectLigninaes_ES
dc.subjectFibras de carbonoes_ES
dc.subject.otherCarbon fiberses_ES
dc.subject.otherLignines_ES
dc.subject.otherElectrospinninges_ES
dc.subject.otherPhosphorus surface groupses_ES
dc.titleNovel lignin-based fibrous carbon materialses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.centroE.T.S.I. Industriales_ES
dc.relation.eventtitleInternational Congress on Chemical Engineering (ICCE)es_ES
dc.relation.eventplaceMadrid (España)es_ES
dc.relation.eventdateJulio 2014es_ES


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