Cation template assisted oligoethylene glycol desymmetrization by intramolecular Cannizzaro reaction of topologically remote aldehydes.

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dc.centroFacultad de Cienciases_ES
dc.contributor.authorRuiz-Sanchez, Antonio Jesus
dc.contributor.authorVida-Pol, Yolanda
dc.contributor.authorSuau Suárez, Rafael
dc.contributor.authorPérez-de-Inestrosa-Villatoro, Ezequiel
dc.date.accessioned2024-09-25T06:41:43Z
dc.date.available2024-09-25T06:41:43Z
dc.date.issued2008
dc.departamentoQuímica Analítica
dc.descriptionPolítica de acceso abierto tomada de: https://v2.sherpa.ac.uk/id/publication/15869es_ES
dc.description.abstractOligoethylene glycol chains containing 2–5 ethylene glycol units, and possessing a benzyl alcohol and a benzoic acid end groups, can be quantitatively obtained by intramolecular Cannizzaro reaction of the corresponding remote benzaldehyde end groups. The process is quite effective if a complex with an appropriate cation is formed to allow the two aldehyde groups to be spatially confined near enough each other for the intramolecular redox process.es_ES
dc.identifier.doi10.1016/j.tet.2008.10.015
dc.identifier.urihttps://hdl.handle.net/10630/33122
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectAldehídoses_ES
dc.subject.otherOligoethylene glycol desymmetrizationes_ES
dc.subject.otherCannizzaro reactiones_ES
dc.subject.otherCation templatees_ES
dc.titleCation template assisted oligoethylene glycol desymmetrization by intramolecular Cannizzaro reaction of topologically remote aldehydes.es_ES
dc.typejournal articlees_ES
dc.type.hasVersionAMes_ES
dspace.entity.typePublication
relation.isAuthorOfPublication41ad1836-4116-4322-9338-fe908247f628
relation.isAuthorOfPublication98747537-47b0-44b3-8957-b82ffe8b4cf3
relation.isAuthorOfPublication.latestForDiscovery41ad1836-4116-4322-9338-fe908247f628

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