Cation template assisted oligoethylene glycol desymmetrization by intramolecular Cannizzaro reaction of topologically remote aldehydes.
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Elsevier
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Oligoethylene glycol chains containing 2–5 ethylene glycol units, and possessing a benzyl alcohol and a benzoic acid end groups, can be quantitatively obtained by intramolecular Cannizzaro reaction of the corresponding remote benzaldehyde end groups. The process is quite effective if a complex with an appropriate cation is formed to allow the two aldehyde groups to be spatially confined near enough each other for the intramolecular redox process.
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Política de acceso abierto tomada de: https://v2.sherpa.ac.uk/id/publication/15869
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